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Nanocrystal Assemblies: Current Advances and Open Problems

delete2024-05-30
delete10
PRE
AI
C
Carlos L. Bassani
G
Greg van Anders
U
Uri Banin
D
Dmitry Baranov
陈茜 cover
陈茜 (Qian Chen)
M
Marjolein Dijkstra
M
Michael S. Dimitriyev
E
Efi Efrati
J
Jordi Faraudo
O
Oleg Gang
N
Nicola Gaston
R
Ramin Golestanian
G
Guillermo Iván Guerrero-García
M
Michael Gruenwald
A
Amir Haji‐Akbari
M
María Ibáñez
M
Matthias Karg
T
Tobias Kraus
B
Byeongdu Lee
R
Reid C. Van Lehn
R
Robert J. Macfarlane
B
Bortolo Matteo Mognetti
A
Arash Nikoubashman
S
Saeed Osat
O
Oleg V. Prezhdo
G
Grant M. Rotskoff
L
Leonor Saiz
A
An‐Chang Shi
S
Sara E. Skrabalak
I
Ivan I. Smalyukh
M
Mario Tagliazucchi
D
Dmitri V. Talapin
A
Alexei V. Tkachenko
S
Sergei Tretiak
D
David Vaknin
A
Asaph Widmer‐Cooper
G
Gerard C. L. Wong
X
Xingchen Ye
S
Shan Zhou
E
Eran Rabani
M
Michael Engel
A
Alex Travesset *
DOI:10.1021/acsnano.3c10201delete
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Abstract

Abstract

En 中文
We explore the potential of nanocrystals (a term used equivalently to nanoparticles) as building blocks for nanomaterials, and the current advances and open challenges for fundamental science developments and applications. Nanocrystal assemblies are inherently multiscale, and the generation of revolutionary material properties requires a precise understanding of the relationship between structure and function, the former being determined by classical effects and the latter often by quantum effects. With an emphasis on theory and computation, we discuss challenges that hamper current assembly strategies and to what extent nanocrystal assemblies represent thermodynamic equilibrium or kinetically trapped metastable states. We also examine dynamic effects and optimization of assembly protocols. Finally, we discuss promising material functions and examples of their realization with nanocrystal assemblies.
Keywords:
nanocrystal
nanoparticle
quantum dots
nanocrystal assembly
colloidal crystal
superlattice
self-assembly
assembly protocols
structureprediction
material properties

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ACS Nano
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