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Nanoparticle/Polyelectrolyte Complexes for Biomimetic Constructs

delete2021-10-27
delete21
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OA
AI
Y
Yixuan Yin
T
Tan Liu
B
Beibei Wang
B
Bangqi Yin
杨
杨阳 (Yang Yang)
T
Thomas P. Russell *
史
史少伟 (Shaowei Shi) *
DOI:10.1002/adfm.202108895delete
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摘要

摘要

En 中文
Constructing all-aqueous systems with tailored geometries can generate a new class of biomimetic materials, a fascinating but challenging goal to achieve. Here, by taking advantage of the interfacial complexation of a polyelectrolyte (PE) and cellulose nanocrystals (CNCs), a unique interfacial PE/CNC complex is demonstrated for the stabilization of aqueous two-phase systems and for the fabrication of all-aqueous double emulsions and 3D constructs. The thickness of PE/CNC complex can be effectively adjusted by tuning the osmotic stress imbalance between the two aqueous phases and, during the formation and thickening of PE/CNC complex, individual assemblies can be connected to design hierarchical all-aqueous structures. This new platform affords tremendous potential for engineering biomimetic constructs with advanced functionality, that can be used for chemical separation, delivery, and biphasic cascading reaction vessels.
Keyword:
3D printing
aqueous-two phase systems
cellulose nanocrystals
complexation
microcapsules
polyelectrolyte

期刊

Advanced Functional Materials 封面图
Advanced Functional Materials
IF:
19
论文数:
3.5W
被引数:
32.1W

机构

U
university of massachusetts system
学者数:
3.9W
论文数: 3.6W
被引数: 42
B
Beijing University of Chemical Technology
学者数:
3.1W
论文数: 2.2W
被引数: 4.5W
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