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Near-optimal protocols in complex nonequilibrium transformations

delete2016-08-29
delete43
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OA
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T
Todd R. Gingrich *
G
Grant M. Rotskoff
G
Gavin E. Crooks
P
Phillip L. Geissler
DOI:10.1073/pnas.1606273113delete
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摘要

摘要

En 中文
The development of sophisticated experimental means to control nanoscale systems has motivated efforts to design driving protocols that minimize the energy dissipated to the environment. Computational models are a crucial tool in this practical challenge. We describe a general method for sampling an ensemble of finite-time, nonequilibrium protocols biased toward a low average dissipation. We show that this scheme can be carried out very efficiently in several limiting cases. As an application, we sample the ensemble of low-dissipation protocols that invert the magnetization of a 2D Ising model and explore how the diversity of the protocols varies in response to constraints on the average dissipation. In this example, we find that there is a large set of protocols with average dissipation close to the optimal value, which we argue is a general phenomenon.
Keyword:
nonequilibrium
irreversible thermodynamics
entropic sampling methods
Metropolis algorithm
Ising model
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期刊

P
Proceedings of the National Academy of Sciences of the United States of America
IF:
9.1
论文数:
10.8W
被引数:
73.5W

机构

U
University of California Berkeley
学者数:
3.5W
论文数: 2.8W
被引数: 11.3W
University of California System 封面图
University of California System
学者数:
37.6W
论文数: 33.8W
被引数: 6.6K
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