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Optical Atomic Switch utilizing a Molecular Junction

delete2025-12-10
delete0
PRE
AI
R
Risako Hamase
K
Kanji Homma
T
Tomoaki Nishino
S
Satoshi Kaneko
K
Kazuhito Tsukagoshi
DOI：10.1039/D5TC03002Adelete
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摘要

摘要

En 中文
光学原子开关因其快速开关速度、低能耗以及与量子信息技术的兼容性而引起了广泛关注。尽管已通过扫描探针技术演示了光激发下的原子调制，但在可操作设备中控制原子运动仍是对实际应用的关键挑战。本研究中，我们操作了光学原子开关，并研究了分子效应对电导调制的影响。采用机械可控断裂结技术制备了包含C 60、联吡啶和丁二胺的单分子结。光照射在所有分子结中诱导了电导增强。对开态和关态下电流-电压特性的分析表明，原子运动调制了分子与电极之间的电子耦合。不同分子结的系统比较显示，分子刚性显著影响光学电导调制，其中像丁二胺这样的柔性分子对初始电导状态的依赖性较弱。

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J
j. mater. chem. c
IF:
0
论文数:
941
被引数:
1

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