.png){kind=icon}
返回
Ordered polyelectrolyte multilayers. Rules governing layering in organic binary multilayers
.png){kind=icon}
PRE
AI
DOI：10.1021/ja0283807.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
We study the growth and internal structure of polyelectrolyte multilayers obtained by combining three polyanions with nine polycations of the ionene family, of systematically varied chemical architecture. We find that, contrary to a generally held belief, ordered organic multilayers are by no way exceptional, provided one of the polyelectrolytes bears groups which induce structure in water, such as long hydrophobic segments or mesogenic groups. However, this condition is not sufficient, as order will or will not emerge in the multilayer depending on the specific pairing of the polyelectrolytes. The results support the notion that layering in the multilayer results from some degree of prestructuring of a water-swollen layer adsorbed during each step of deposition. These findings pave the way to new possible uses of polyelectrolyte multilayers, for example, for applications requiring preferential alignment or strong confinement of specific functional groups.
Keyword:
X-RAY REFLECTIVITY
STEPWISE FORMATION
INTERNAL STRUCTURE
NEUTRON
FILMS
ADSORPTION
IONOMERS
POLYMERS
COATINGS
BUILDUP
AI总结
对已上传原文的论文进行重点信息的提取，主要内容包括：简要概述、研究摘要、背景介绍、关键亮点、图文解析、展望与总结。
期刊
IF:
15.6
论文数:
20.0W
被引数:
60.2W
机构
暂无机构信息
引用论文
.png){kind=icon}
查看更多内容