Polynorbornene-based Template for Polymer Synthesis

doi:10.1246/bcsj.20170354

2017-11-28

Guoqiao Lai

Tien‐Yau Luh *

DOI：10.1246/bcsj.20170354

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摘要

En 中文

The recent advances in the use of rigid polynorbornene or polycyclobutene as template for the synthesis of different polymers with well-defined degree of polymerization and narrow polydispersity are reviewed. Polynorbornene and polycyclobutene templates containing fused N-arylpyrrolidene pendants are synthesized by ruthenium or molybdenum-catalyzed ring opening metathesis polymerization (ROMP) of the corresponding monomers. Since these polymerizations are living, the templates thus have well-defined degree of polymerization and narrow polydispersity. Monomers are linked to the template polymer via ester linkage. After polymerization and hydrolysis, the poly-carboxylic acid template can easily be separated from the neutral polyalcohol daughter polymer.

Keyword:

OPENING METATHESIS POLYMERIZATION

SELF-REPLICATING SYSTEMS

LADDERPHANES

PENDANTS

STRATEGY

MONOMER

ESTERS

ROMP

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期刊

Bulletin of the Chemical Society of Japan

IF:

3.8

论文数:

9.0K

被引数:

1.1W

机构

hangzhou normal university

学者数:

1.3W

论文数: 7.8K

被引数: 8

National Taiwan University

学者数:

4.7W

论文数: 4.2W

被引数: 3.6W

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