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Preparation and Corrosion Resistance Mechanism of Magnesium–Lithium Alloy Micro-arc Oxidation/Quaternary LDHs@GO Self-healing Composite Film

delete2025-07-03
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PRE
AI
Z
Zhenzhen Tian
F
Fubing Yu
Y
Yan Zhou
姚文辉 cover
姚文辉 (Wenhui Yao)
袁媛 cover
袁媛 (Yuan Yuan)
谢治辉 cover
谢治辉 (Zhihui Xie)
Y
Yanlong Ma
A
Andrej Atrens
L
Liang Wu *
DOI:10.1007/s40195-025-01892-4delete
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Abstract

Abstract

En 中文
Micro-arc oxidation (MAO) film can only provide common mechanical protection for magnesium (Mg)–lithium (Li) alloys. These alloys are susceptible to severe localized corrosion, if the MAO film is disrupted. This work reports the successful hydrothermal preparation of a MgLiAlCe-LDHs@GO film on a MAO-coated Mg–Li alloy following Ce confinement. The graphene oxide (GO) sheet increased the diffusion path of the corrosive media, and the addition of rare-earth cerium ions (Ce3+) endowed the film with a certain self-healing ability, which significantly improved the corrosion resistance of the film, and the corrosion current density (icorr) reached 3.27 × 10−8 A cm−2. The synergistic action of GO and Ce3+ can achieve long-term corrosion protection for the substrate. The corrosion resistance mechanism of MgLiAlCe-LDHs@GO film was discussed by the scanning vibration electrode technique (SVET).
Keywords:
Micro-arc oxidation (MAO)
Magnesium–lithium alloy
Quaternary layer doubled hydroxides (LDHs)
Graphene oxide
Corrosion mechanism

Journal

A
Acta Metallurgica Sinica-English Letters
IF:
3.9
Papers:
79
Citations:
5.0K

Organization

C
centre for advanced materials and processing
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1
Papers: 1
Citations: 0
C
College of Materials Science and Engineering
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1.4K
Papers: 393
Citations: 0
C
College of Chemistry and Chemical Engineering
Scholars:
1.1K
Papers: 312
Citations: 1
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