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Progress in Research into 2D Graphdiyne-Based Materials

delete2018-07-26
delete793
PRE
AI
黄
黄长水 (Changshui Huang)
Y
Yongjun Li
N
Ning Wang
Y
Yurui Xue
Z
Zicheng Zuo
H
Huibiao Liu
李
李玉良 (Yuliang Li) *
DOI:10.1021/acs.chemrev.8b00288delete
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摘要

摘要

En 中文
Graphynes (GYs) are carbon allotropes with single-atom thickness that feature layered 2D structure assembled by carbon atoms with sp- and sp(2)- hybridization form. Various functional theories have predicted GYs to have natural band gap with Dirac cones structure, presumably originating from inhomogeneous pi-bonding between those carbon atoms with different hybridization and overlap of the carbon 2p(z) orbitals. Among all the GYs, graphdiyne (GDY) was the first reported to be prepared practically and, hence, attracted the attention of many researchers toward this new planar, layered material, as well as other GYs. Several approaches have been reported to be able to modify the band gap of GDY, containing invoking strain, boron/nitrogen doping, nanoribbon architectures, hydrogenation, and so on. GDY has been well-prepared in many different morphologies, like nanowires, nanotube arrays, nanowalls, nanosheets, ordered stripe arrays, and 3D framwork. The fascinating structure and electronic properties of GDY make it a potential candidate carbon material with many applications. It has recently revealed the practicality of GDY as catalyst; in rechargeable batteries, solar cells, electronic devices, magnetism, detector, biomedicine, and therapy; and for gas separation as well as water purification.
Keyword:
OXYGEN REDUCTION REACTION
NITROGEN-DOPED GRAPHDIYNE
BORON-NITRIDE ANALOG
LITHIUM-ION BATTERY
ALPHA-GRAPHYNE NANORIBBONS
CALCIUM-DECORATED GRAPHYNE
METAL-FREE ELECTROCATALYST
HYDROGEN STORAGE CAPACITY
EXTERNAL ELECTRIC-FIELD
IN-SITU SYNTHESIS
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期刊

Chemical Reviews 封面图
Chemical Reviews
IF:
55.8
论文数:
568
被引数:
24.7W

机构

I
institute of chemistry, cas
学者数:
4.6K
论文数: 3.9K
被引数: 6
C
chinese academy of sciences
学者数:
56.7W
论文数: 45.0W
被引数: 704
引用论文

引用论文

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