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Push-push and push-pull polystannanes
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DOI：10.1039/c8dt03043j.png)
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The synthesis and characterization of polystannanes with push or pull moieties attached to the tin backbone are described. Precursor tetra aryl- (1, 2) stannanes were converted to mono- (3) and dichloro- (4, 5) stannanes by either sequential chlorination or by redistribution reactions with SnCl4. Compounds 4 and 5 were transformed to polymerisable tin dihydride monomers 6 and 7 using a large excess (10x) of NaBH4. Homopolymer 8 with electron donating aryl substituents (p-MeOC6H4-) was synthesized by dehydrogenative polymerization using Wilkinson's catalyst. Attempts to prepare the homopolymer 9 with electron withdrawing aryl substituents (p-CF3C6H4-) from the dehydrocoupling of 7 using similar conditions led only to the formation of low molecular weight oligomeric species. Two alternating polymers, 10 and 11, were synthesized by condensation polymerization of (n-Bu)(2)Sn(NEt2)(2) with monomers 6 or 7. The first was a push-push alternating polymer, 10, comprised of a repeating unit consisting of two different electron donating groups (p-MeOC6H4-, n-Bu) at neighboring tin centres. The second was a push-pull alternating polymer, 11, bearing both an electron donating group (n-Bu) and a strongly electron withdrawing substituent (p-CF3C6H4-) at neighboring tin atoms. All small molecule stannanes and tin-containing polymers were characterized by NMR (H-1, C-13, Sn-119, and where required F-19) spectroscopy, MS or EA. The absolute molecular weights of tin polymers (8, 10, 11) were determined by triple detection GPC and in the range of 1.07 x 10(4) to 1.95 x 10(4) Da. Rapid photodegradation of polymers was observed by UV-Vis spectroscopy, with a slower degradation observed for the push-pull polymer, 11, compared to the push-push polymer, 10.
Keyword:
POLYMERS
DEHYDROPOLYMERIZATION
NMR
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期刊
IF:
3.3
论文数:
3.3W
被引数:
7.5W
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