.png){kind=icon}
返回
Responsive Interfacial Assemblies Based on Charge-Transfer Interactions
.png){kind=icon}
PRE
AI
DOI：10.1002/anie.202111252.png)
.png){kind=icon}
原文求助.png){kind=icon}
分享.png){kind=icon}
收藏
摘要
En 中文
Charge transfer (CT) interactions have been widely used to construct supramolecular systems, such as functional nanostructures and gels. However, to date, there is no report on the generation of CT complexes at the liquid-liquid interface. Here, by using an electron-deficient acceptor dissolved in water and an electron-rich donor dissolved in oil, we present the in situ formation and assembly of CT complex surfactants (CTCSs) at the oil-water interface. With time, CTCSs can assemble into higher-order nanofilms with exceptional mechanical properties, allowing the stabilization of liquids and offering the possibility to structure liquids into nonequilibrium shapes. Moreover, due to the redox-responsiveness of the electron-deficient acceptor, the association and dissociation of CTCSs can be reversibly manipulated in a redox process, leading to the switchable assembly and disassembly of the resultant constructs.
Keyword:
charge transfer interaction
oil-water interface
self-assembly
structured liquid
surfactant
期刊
IF:
16.9
论文数:
5.7W
被引数:
53.0W
机构
引用论文
.png){kind=icon}
Superamphiphiles Based on Directional Charge-Transfer Interactions: From Supramolecular Engineering to Well-Defined Nanostructures基于定向电荷转移相互作用的超两亲物: 从超分子工程到定义明确的纳米结构
PREAI
分享收藏
分享收藏
查看更多内容