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Reversible potassium-ion intercalation into graphite electrodes in glyoxal-based electrolytes

delete2021-04-01
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L
Lukas Medenbach
L
Lea C. Meyer
A
Andrea Balducci *
DOI:10.1016/j.elecom.2021.107001delete
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Abstract

Abstract

En 中文
In this work the use of the solvents 1,1,2,2-tetramethoxyethan (tetramethylglyoxal, TMG) and 1,1,2,2-tetraethoxyethan (tetraethylglyoxal, TEG) in potassium-based systems is reported for the first time. We show that utilizing electrolytes based on these solvents, potassium bis(fluorosulfonyl)imide (KFSI) and the additive vinyl ethylene carbonate (VEC), it is possible to reversibly intercalate and extract potassium-ions into and from graphite electrodes. Graphite electrodes in combination with the electrolyte 1.5 M KFSI in TEG/VEC display an intercalation capacity of 200 mAh g-1, stable for 40 cycles at C/10. This performance is comparable to that achieved with conventional organic electrolytes.
Keywords:
Potassium-ion battery
Graphite
Electrolyte
Glyoxal
Intercalation
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Journal

Electrochemistry Communications cover
Electrochemistry Communications
IF:
4.2
Papers:
1.6K
Citations:
1.6W

Organization

F
Friedrich Schiller University of Jena
Scholars:
1.9W
Papers: 1.5W
Citations: 25
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