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Role of solvent in the dehydrogenation of ammonia borane over supported ruthenium nanoparticles
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DOI：10.1016/j.jcat.2026.117098.png)
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Abstract
En 中文
• Rates of H2 release higher in protic solvents compared to aprotic solvents • Apparent activation energies were similar across protic solvents but had different pre-exponential factors. • AB dehydrogenation rates decreased with kinetic diameter of the solvent molecule for protic solvents. • Differences in rates and apparent rate constants due to either entropic effects or site blockage.
Journal
J
IF:
6.5
Papers:
1.2W
Citations:
5.1W
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