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Self-assembled second order nonlinear optical multilayer azo polymer
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DOI：10.1002/marc.1997.030180601.png)
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An epoxy based polymer with nonlinear optical azo chromophores was designed to contain anionic groups to induce water solubility and self assembly. Using this polyanion with a polycation, multilayers were prepared on a glass substrate by alternating adsorption from dilute aqueous solutions. The azo chromophores in the confined layer of the polyanion in the multilayer films self-assemble into a noncentrosymmetric alignment and demonstrate second order optical nonlinearity (d(33) = 19 pm/V).
Keyword:
2ND HARMONIC-GENERATION
LANGMUIR-BLODGETT-FILMS
BY-LAYER MANIPULATION
2ND-HARMONIC GENERATION
CONJUGATED POLYIONS
CONDUCTING POLYMERS
HETEROSTRUCTURES
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4.3
论文数:
8.5K
被引数:
1.6W
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Self-assembled chromophoric NLO-active monolayers. X-ray reflectivity and second-harmonic generation as complementary probes of building block-film microstructure relationships.png)
LANGMUIR
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