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“Silatranization”: Surface modification with silatrane coupling agents
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DOI：10.1016/j.cis.2025.103649.png)
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摘要
En 中文
• 硅杂烷笼合物比典型硅烷更容易形成自组装单层。
• 强韧的硅杂烷笼合物允许引入广泛的官能团。
• 它们可在水、烃类或混合介质中工作，提高了反应的灵活性。
• 硅杂烷沉积可被酸催化。
• 后处理（如电化学氧化）可确保获得不含三乙醇胺的吸附层。
Keyword:
Silatrane
Surface modification
Coupling agents
Self-assembled monolayer
Organosilicon chemistry
Hybrid materials
AFM
atomic force microscopy
APS
1-(3-aminopropyl)silatrane
APTES
3-aminopropyltriethoxysilane
APTMS
3-aminopropyltrimethoxysilane
CP/MAS NMR
cross polarization/magic angle spinning NMR
Cp*
pentamethylcyclopentadienyl
CV
cyclic voltammetry
DMAP
4-dimethylaminepirydine
DSPEC
dye-sensitized photoelectric cell
DSSC
dye-sensitized solar cell
FA
formic acid
FE
Faradaic efficiency
IEP
isoelectric point
IQE
internal quantum efficiency
ITO
indium tin oxide
MPS
1-(3-mercaptopropyl)silatrane
MPTMS
(3-mercaptopropyl)trimethoxysilane
NP
nanoparticle
PC
polycarbonate
PCE
power conversion efficiency
PET
poly(ethylene terephthalate)
PMMA
poly(methyl methacrylate)
RI
refractive index
RMS
root mean square
r.t.
room temperature
SAM
self-assembling monolayer
SCA
silane coupling agent
SilCA
silatrane coupling agent
TEMPO
(2,2,6,6-tetramethylpiperidin-1-yl)oxyl
TEOA
triethanolamine
TESPD
bis(triethoxysilylpropyl)disulfide
TG
thermogravimetric analysis
XPS
X-ray photoelectron spectroscopy
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期刊
IF:
19.3
论文数:
2.9K
被引数:
3.0W
机构
引用论文
Impressivephenol hydroxylation activity using Fe–Ti-TUD-1 synthesized from silatrane via sol–gel process通过溶胶-凝胶法制备的Fe–Ti-TUD-1展现出令人印象深刻的酚类羟基化活性。
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