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Single-file dynamics with different diffusion constants

delete2008-11-14
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T
Tobias Ambjörnsson *
S
Silbey, Robert J.
L
Lizana, Ludvig
M
Michael A. Lomholt
DOI:10.1063/1.3009853delete
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摘要

摘要

En 中文
We investigate the single-file dynamics of a tagged particle in a system consisting of N hardcore interacting particles (the particles cannot pass each other) which are diffusing in a one-dimensional system where the particles have different diffusion constants. For the two-particle case an exact result for the conditional probability density function (PDF) is obtained for arbitrary initial particle positions and all times. The two-particle PDF is used to obtain the tagged particle PDF. For the general N-particle case (N large) we perform stochastic simulations using our new computationally efficient stochastic simulation technique based on the Gillespie algorithm. We find that the mean square displacement for a tagged particle scales as the square root of time (as for identical particles) for long times, with a prefactor which depends on the diffusion constants for the particles; these results are in excellent agreement with very recent analytic predictions in the mathematics literature.
Keyword:
aggregation
diffusion
numerical analysis
probability
stochastic processes
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期刊

Journal of Chemical Physics 封面图
Journal of Chemical Physics
IF:
3.1
论文数:
7.2W
被引数:
23.2W

机构

U
University of Copenhagen
学者数:
7.6W
论文数: 6.6W
被引数: 86
N
niels bohr institute
学者数:
4.9K
论文数: 4.1K
被引数: 17
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