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Small He clusters with aromatic molecules

delete2001-08-01
delete59
PRE
AI
U
U. Even *
I
I. Al-Hroub
J
Joshua Jortner
DOI:10.1063/1.1385154delete
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摘要

摘要

En 中文
Excitation spectra of ultracold (T=0.4 K) large aromatic molecules (naphthalene, anthracene, and tetracene) solvated by a few (1-16) He atoms are reported. Measured spectral shifts and vibronic excitations for a series of mass selected He clusters are presented. Clusters on aromatic molecules with an increasing number of rings show unexpected, and size-dependent, spectral effects. We suggest that the novel spectroscopic features are due to the anisotropic delocalization of the He atoms on the surface of the aromatic molecule. (C) 2001 American Institute of Physics.
Keyword:
RARE-GAS HETEROCLUSTERS
ELECTRONIC SPECTRAL SHIFTS
VANDERWAALS COMPLEXES
HELIUM CLUSTERS
SUPERSONIC JET
SPECTROSCOPY
STATE
EXCITATIONS
SOLVATION
DYNAMICS
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期刊

Journal of Chemical Physics 封面图
Journal of Chemical Physics
IF:
3.1
论文数:
7.2W
被引数:
23.2W

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