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Solid-Liquid Self-Adaptive Polymeric Composite

delete2016-01-14
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PRE
AI
P
Pei Dong
A
Alin Cristian Chipara
P
Phillip E. Loya
Y
Yingchao Yang
L
Liehui Ge
S
Sidong Lei
B
Bo Li
G
Gustavo Brunetto
L
Leonardo D. Machado
L
Liang Hong
Q
Qizhong Wang
H
Hua Guo
E
Emilie Ringe
D
Douglas S. Galvão
R
Róbert Vajtai
M
Mircea Chipara
M
Ming Tang
Jun Lou 封面图
Jun Lou (Jun Lou)
P
Pulickel M. Ajayan *
DOI:10.1021/acsami.5b10667delete
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摘要

摘要

En 中文
A solid liquid self-adaptive composite (SAC) is synthesized using a simple mixing evaporation protocol, with poly(dimethylsiloxane) (PDMS) and poly(vinylidene fluoride) (PVDF) as active constituents. SAC exists as a porous solid containing a near equivalent distribution of the solid (PVDF) liquid (PDMS) phases, with the liquid encapsulated and stabilized within a continuous solid network percolating throughout the structure. The pores, liquid, and solid phases form a complex hierarchical structure, which offers both mechanical robustness and a significant structural adaptability under external forces. SAC exhibits attractive self-healing properties during tension, and demonstrates reversible self-stiffening properties under compression with a maximum of 7-fold increase seen in the storage modulus. In a comparison to existing self-healing and self-stiffening materials, SAC offers distinct advantages in the ease of fabrication, high achievable storage modulus, and reversibility. Such materials could provide a new class of adaptive materials system with multifunctionality, tunability, and scale-up potentials.
Keyword:
hierarchical structure
self-adaptive
self-healing
self-stiffening
solid-liquid composite
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期刊

ACS Applied Materials and Interfaces 封面图
ACS Applied Materials and Interfaces
IF:
8.2
论文数:
6.1W
被引数:
38.7W

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Rice University
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university of texas system
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被引数: 210
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universidade estadual de campinas
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3.3W
论文数: 2.3W
被引数: 19
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