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Stabilizing Fluorine-π Interactions

delete2017-05-02
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PRE
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李平 封面图
李平 (Ping Li)
J
Josef M. Maier
E
Erik C. Vik
C
Christopher J. Yehl
B
Brent E. Dial
A
Amanda E. Rickher
M
Mark D. Smith
P
Perry J. Pellechia
K
Ken D. Shimizu *
DOI:10.1002/anie.201702950delete
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摘要

摘要

En 中文
A series of N-arylimide molecular balances were designed to study and measure fluorine-aromatic (F-pi) interactions. Fluorine substituents gave rise to increasingly more stabilizing interactions with more electron-deficient aromatic surfaces. The attractive F-pi interaction is electrostatically driven and is stronger than other halogen-pi interactions.
Keyword:
electrostatic interactions
fluorine
F-pi interactions
supramolecular chemistry
pi interactions
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期刊

Angewandte Chemie-International Edition 封面图
Angewandte Chemie-International Edition
IF:
16.9
论文数:
5.7W
被引数:
53.0W

机构

U
University of South Carolina System
学者数:
1.6W
论文数: 1.5W
被引数: 27
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