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Stackable molecular chairs

delete2019-01-01
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PRE
AI
H
Han Xie
Z
Zhi‐Quan Lei
R
Radoslav Z. Pavlović
J
Judith C. Gallucci
J
Jovica D. Badjić *
DOI:10.1039/c9cc01664cdelete
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摘要

摘要

En 中文
We describe the design, preparation and assembly of chair-shaped molecules, comprising a tris-bicyclo[2.2.1]heptane hub that extends into three phthalimides carrying amino acids or short peptides. In water, molecular chairs stack in an antiparallel manner to give hexavalent dendritic structures, in spite of holding equal charges. The here described strategy for increasing the multivalency of peptides is easy to implement in practice, therefore holding potential for creating novel soft materials and therapeutics.
Keyword:
SUPRAMOLECULAR CHEMISTRY
GUEST ENCAPSULATION
HOFMEISTER
BINDING
COMPLEXES
WATER
SALT
BASKETS
BONDS
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期刊

Chemical Communications 封面图
Chemical Communications
IF:
4.2
论文数:
5.9W
被引数:
16.5W

机构

U
University System of Ohio
学者数:
15.5W
论文数: 13.0W
被引数: 200
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