State-independent ionic conductivity

Joyce Barclay

doi:10.1126/science.adk0786

2025-12-18

PRE

Alyssa‐Jennifer Avestro

José N. Canongia Lopes

Chris Groves

J.C. Jones

Paul R. McGonigal *

DOI：10.1126/science.adk0786

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从液态到固态的转变通常会引入离子导电率的间断性。在液相中，离子导电率遵循阿伦尼乌斯关系。然而，如冻结这样的剧烈相变会导致转变温度处离子导电率的下降，因为离子在固态中的迁移率远低于液态。Barclay等人设计了一种基于环丙烯鎓盐的有机电解质，其离子导电率在液固相变边界处不会出现剧烈下降。这一特性是通过由液晶相区域连接液相和固相区域实现的。关键因素在于较弱的阳离子-阴离子相互作用和相当大的结构自由度。——Marc S. Lavine

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