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Stepwise structure evolution from 2D cluster-based frameworks to silver(I) clusters
DOI:10.1039/d2cc04623g.png)
摘要
En 中文
A pair of 2D chiral frameworks, R-Ag-5-1 and S-Ag-5-1, with orange fluorescence were successfully synthesized. They were transformed to a thermodynamically favored denser stacking, R-Ag-5-3 and S-Ag-5-3, accompanied by a change in the luminescence and activating the CPL signal. The capture and structural determination of the intermediates (R-Ag-5-2 and S-Ag-5-2) reveal that the coordination instability of Na+ ions is the main cause of this transition.
Keyword:
IONS
期刊
IF:
4.2
论文数:
5.9W
被引数:
16.5W
机构
引用论文
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