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Stepwise structure evolution from 2D cluster-based frameworks to silver(I) clusters

delete2022-01-01
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PRE
AI
Q
Qiu‐Xu Zang
王朝阳 封面图
王朝阳 (Zhao‐Yang Wang)
Y
Yao Li
X
Xi‐Ming Luo
李海洋 封面图
李海洋 (Haiyang Li)
Y
Yanan Si
臧
臧双全 (Shuang‐Quan Zang) *
DOI:10.1039/d2cc04623gdelete
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摘要

摘要

En 中文
A pair of 2D chiral frameworks, R-Ag-5-1 and S-Ag-5-1, with orange fluorescence were successfully synthesized. They were transformed to a thermodynamically favored denser stacking, R-Ag-5-3 and S-Ag-5-3, accompanied by a change in the luminescence and activating the CPL signal. The capture and structural determination of the intermediates (R-Ag-5-2 and S-Ag-5-2) reveal that the coordination instability of Na+ ions is the main cause of this transition.
Keyword:
IONS

期刊

Chemical Communications 封面图
Chemical Communications
IF:
4.2
论文数:
5.9W
被引数:
16.5W

机构

Z
Zhengzhou University
学者数:
6.8W
论文数: 4.4W
被引数: 8.5W
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