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Structure and solvation in ionic liquids

delete2007-06-21
delete332
PRE
AI
C
CarrollMichael (Christopher Hardacre) *
J
John D. Holbrey
M
M. Nieuwenhuyzen
T
Tristan G. A. Youngs
DOI：10.1021/ar700068xdelete
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摘要

摘要

En 中文
This Account describes experimental data used to understand the structure of ionic liquids and solute-solvent interactions of both molecular solutes and dissolved metal complexes. In general, the structures of the ionic liquids determined from experimental data show good agreement with both simulated structures and solid-state structures. For all ionic liquids studied, strong charge ordering is found leading to long-range order even in the presence of a solute. For dissolved metal complexes, the ionic liquid is not innocent and a clear dependence on the speciation is observed with variations in both the cation and anion.
Keyword:
X-RAY-DIFFRACTION
NEUTRON-DIFFRACTION
ROTATIONAL-ISOMERISM
AROMATIC-COMPOUNDS
LOCAL-STRUCTURE
MOLTEN-SALTS
CHLORIDE
EXAFS
CRYSTALLINE
SURFACE
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期刊

Accounts of Chemical Research 封面图
Accounts of Chemical Research
IF:
17.7
论文数:
6.3K
被引数:
8.7W

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