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Structure interconversion in isomeric guanine derivatives at elevated sample temperature

delete2005-04-08
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DOI:10.1002/rcm.1290060113delete
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摘要

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AbstractGuanine derivatives were examined using the tandem mass spectrometry (MS/MS) method. Isomeric structure differences were explored by means of the unimolecular decomposition spectra of the common ion m/z 151 having the empirical formula of the guanine molecular ion. An interconversion of the isomeric structures as the sample temperature is gradually raised, was observed.

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