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Structure-property relationships in bio-based polybenzoxazines: a comparative study of lignin-derived and flavonoid-based polymers
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DOI：10.1016/j.eurpolymj.2026.114960.png)
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Abstract
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• Bio-based benzoxazines from vanillin, daidzein and naringenin via green synthesis. • Monomer functionality governs thermal, mechanical and moisture-resistance properties. • Daidzein-based thermoset achieves highest Tg (278 °C) and thermal stability. • Naringenin system yields highest hardness (Shore D 93) and lowest water uptake. • Vanillin-based polymer shows best tensile strength for composite matrix applications.
Keywords:
Bio-based benzoxazines
Vanillin
Daidzein
Naringenin
Furfurylamine
Renewable resources
Structure–property relationship
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