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Studies on gold-nitrone systems
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DOI：10.1039/c8dt04254c.png)
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摘要
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A series of novel Au(I)-nitrone complexes with specific catalytic properties were prepared. Furthermore, Au(I)-and Au(III)-oxadiazole complexes were formed by a novel Au-generated nitrile-nitrone [3 + 2] cycloaddition, and the crystal structures of Au(I)-nitrones as well as the Au(I)-and Au(III)-oxadiazole complexes were studied (X-ray). A useful one-pot Au(III)-mediated cycloaddition method was developed for the formation of a number of dihydro-1,2,4-oxadiazoles, involving in situ formation of Au(III)-oxadiazole complexes. The observed Au(I) and Au(III) dual selective reactivity gives new understanding about the Au(I)-and Au(III)-nitrone chemistry.
Keyword:
PLATINUM-BOUND ORGANONITRILES
MIXED-LIGAND PT(II)
1,3-DIPOLAR CYCLOADDITION
OXADIAZOLINE COMPLEXES
ONE-POT
NITRILES
1,2,4-OXADIAZOLES
CATALYSTS
GOLD(III)
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期刊
IF:
3.3
论文数:
3.3W
被引数:
7.5W
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Design, Synthesis, and Structure-Activity Relationships of 3,4,5-Trisubstituted 4,5-Dihydro-1,2,4-oxadiazoles as TGR5 Agonists.png)
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