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Supramolecular Polymerization of Antiaromatic 5; 15-Dioxaporphyrin
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DOI：10.1039/D6NJ01964A.png)
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Abstract
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Supramolecular polymerization driven by π-π interaction of antiaromatic compounds was investigated using 5; 15-dioxaporphyrin bearing hydrogen-bonding amide groups. The variable-temperature UV/vis/NIR absorption spectra revealed the formation of J-type assemblies via a nucleation-and-elongation mechanism; as further confirmed by atomic force microscopy.
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