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Switchable solvents
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DOI：10.1039/c0sc00568a.png)
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Abstract
En 中文
Switchable solvents are a unique class of solvents that were developed to facilitate both reaction and subsequent product separation. Their built-in separation ability for facile product recovery is paramount to achieving chemical processes that are both economically competitive and environmentally conscious. Two classes of switchable solvents are discussed: 1) piperylene sulfonea volatile and recycle DMSO substitute and 2) one and two-component reversible ionic liquids-solvent systems that can be switched back and forth between molecular liquids and ionic liquids.
Keywords:
SUPERCRITICAL CARBON-DIOXIDE
NEAR-CRITICAL WATER
REVERSIBLE IONIC LIQUIDS
GAS-EXPANDED LIQUIDS
ROOM-TEMPERATURE
ASYMMETRIC HYDROGENATION
CO2-EXPANDED METHANOL
ALKYLATION REACTIONS
PIPERYLENE SULFONE
BENIGN MEDIUM
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