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Synergetic Explosive Performance through Cocrystallization
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DOI：10.1021/acs.cgd.0c01267.png)
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摘要
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A 1:2 cocrystal of 4H,8H-difurazano[3,4-b:3',4'-e]pyrazine and hydroxylamine has been prepared that displays 1,3,5-triamino-2,4,6-trinitrobenzene-like sensitivity and performance. Most notably, the detonation properties of the cocrystal are better than that of the hypothetical 1:2 physical mixture and also higher than the theoretically predicted salt, making this a rare example of a cocrystal in which the detonation properties are synergistic. This was achieved through maximizing the intermolecular interactions through several hydrogen bonding and pi-stacking.
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3.4
论文数:
1.6W
被引数:
3.5W
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