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Synthesis and Stereochemical Revision of Violaceoid E; a Polyoxygenated Cyclohexanoid Natural Product Isolated from Aspergillus violaceofuscus Gasperini
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DOI：10.1021/acs.jnatprod.6c00630.png)
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Abstract
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The first concise synthesis of the proposed structure of violaceoid E, possessing a cis-diol moiety, has been achieved. However, the spectroscopic data of the synthetic compound were inconsistent with those of the natural product, suggesting that the genuine violaceoid E might be a trans-diol. An efficient synthesis of our proposed trans-diol-type violaceoid E has also been achieved, enabling the establishment of the absolute configuration of natural violaceoid E.
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