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Tetrylene-Functionalized Si7-Siliconoids
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DOI：10.1021/acs.inorgchem.4c00474.png)
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摘要
En 中文
The core expansion of metallic or metalloid clusters by the addition of further homo- or heteronuclear vertices is pivotal to the nucleation and growth of particles. The exohedral grafting of a low-valent functionality followed by endohedral incorporation have been identified as key steps. Following previous work on the Si-6 series, we now report the synthesis and full characterization of the amidinatotetrylene-functionalized seven-vertex siliconoids Si7R5[E((NBu)-Bu-t)(2)CPh] (E = Si, Ge, Sn). In the case of the silylene derivative, the solid-state structure was determined by single crystal X-ray diffraction.
Keyword:
SILICON CLUSTER
GLOBAL-MINIMUM
QUANTUM DOTS
ENERGY
APPROXIMATION
CORE
BOND
期刊
IF:
4.7
论文数:
4.9W
被引数:
10.5W
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引用论文
Self-assembly of five new organic–inorganic hybrids based on two new flexible tricationic templates基于两个新的柔性三阳离子模板的五个新的有机-无机杂化物的自组装
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分享收藏A heavy analogue of the smallest bridgehead alkene stabilized by a base.png)
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