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The instantaneous fluctuation theorem

delete2013-11-11
delete2
PRE
AI
C
Charlotte F. Petersen *
D
Denis J. Evans
S
Stephen R. Williams
DOI：10.1063/1.4829445delete
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摘要

摘要

En 中文
We give a derivation of a new instantaneous fluctuation relation for an arbitrary phase function which is odd under time reversal. The form of this new relation is not obvious, and involves observing the system along its transient phase space trajectory both before and after the point in time at which the fluctuations are being compared. We demonstrate this relation computationally for a number of phase functions in a shear flow system and show that this non-locality in time is an essential component of the instantaneous fluctuation theorem. (Cd) 2013 AIP Publishing LLC.
Keyword:
DYNAMICAL ENSEMBLES
TIME-REVERSIBILITY
ENTROPY PRODUCTION
VERIFICATION
EQUIVALENCE
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期刊

Journal of Chemical Physics 封面图
Journal of Chemical Physics
IF:
3.1
论文数:
7.2W
被引数:
23.2W

机构

A
Australian National University
学者数:
2.1W
论文数: 2.3W
被引数: 3.9W
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