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The key to the phosphorus heart: mild axial mono-functionalization of phosphorus(V) phthalocyanines

delete2026-03-12
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PRE
AI
A
A.E. Ovchenkova
E
E.A. Safonova *
M
M.A. Polovkova
A
A.G. Martynov
E
E.V. Gorshkov
A
A.Yu. Tsivadze
Y
Yu.G. Gorbunova *
DOI：10.1016/j.inoche.2026.116513delete
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Abstract

Abstract

En 中文
• The first example of axially mono-functionalized P(V) phthalocyanine PcP was obtained. • Mild and selective method enables the synthesis of PcP with two diverse axial ligands. • The approach consists in targeted alkylation of one of the axial OH-groups. • The unsymmetrical PcP is water soluble and exhibits high singlet oxygen quantum yield. • Calculations evidence of enhancement of singlet-triplet spin-orbital coupling in PcP.
Keywords:
Phosphorus(V) phthalocyanine
Axial functionalization
Singlet oxygen
Water solubility
Spin-orbital coupling

Journal

I
Inorganic Chemistry Communications
IF:
5.4
Papers:
1.4K
Citations:
0

Organization

L
lomonosov moscow state university
Scholars:
2.1W
Papers: 1.5W
Citations: 19
R
russian academy of sciences
Scholars:
8.9W
Papers: 5.9W
Citations: 59
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