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Tip-Induced Nitrene Generation

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OA
AI
L
Leonard-Alexander Lieske *
A
Aaron H. Oechsle
I
Igor Rončević
I
Ilias Gazizullin
F
Florian Albrecht
M
Matthias Krinninger
L
Leonhard Grill
F
Friedrich Esch
L
Leo Groß *
DOI：10.1021/acsnano.5c08710delete
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摘要

摘要

En 中文
我们通过尖端诱导化学，以2,5,8-三叠氮基-s-七嗪作为前驱体，在Au(111)上的NaCl双层上合成了三亚硝基-s-七嗪，这是一种具有三个亚硝基中心的小分子。前驱体的叠氮基团发生解离，形成单亚硝基-s-七嗪、二亚硝基-s-七嗪和三亚硝基-s-七嗪，生成了具有一个至三个亚硝基中心的分子。前驱体及其产物通过原子力显微镜和扫描隧道显微镜进行表征。亚硝基间和亚硝基内的交换耦合的对称性破缺DFT和组态相互作用计算表明，S = 1的亚硝基中心之间存在铁磁耦合，导致中性三亚硝基-s-七嗪在气相中具有高自旋七重态基态。在Au(111)上的NaCl双层上，实验与理论结合的结果表明三亚硝基-s-七嗪为具有六重态基态的阴离子。

期刊

ACS Nano 封面图
ACS Nano
IF:
16
论文数:
2.7W
被引数:
25.6W

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I
ibm research europe − zurich, rüschlikon 8803, switzerland
学者数:
4
论文数: 1
被引数: 0
U
University of Graz
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6.1K
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被引数: 8.6K
T
Technical University of Munich
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5.2W
论文数: 3.9W
被引数: 6.2W
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University of Manchester
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论文数: 5.3W
被引数: 7.4W
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