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Transformative 3d-4f coordination cluster carriers
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DOI：10.1039/c8dt02362j.png)
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摘要
En 中文
The aim of this perspective is to summarise the use of the reported 3d-4f Coordination Clusters (CCs) in catalytic reactions and to demonstrate the potential of this emerging field. The pioneering work of Shibasaki, Matsunaga and others, demonstrated the use of 3d-4f in situ systems to catalyse asymmetric organic transformations. Our recent studies show that well characterised 3d-4f CCs catalyse numerous organic transformations and useful mechanistic aspects of their catalysis can be obtained. Furthermore, we have shown that by manipulation of the metal ion coordination environment; the nature of the 3d and lanthanide ions and the organic periphery of the ligand can all improve the efficacy of a 3d-4f CC catalyst. All in situ formed and well characterized 3d-4f CCs involved in catalysis are discussed.
Keyword:
CATALYTIC ASYMMETRIC-SYNTHESIS
RING-OPENING COPOLYMERIZATION
TRANSITION-METAL-COMPLEXES
SCHIFF-BASE LIGAND
BETA-KETO-ESTERS
ALTERNATING COPOLYMERIZATION
MICHAEL ADDITION
CARBON-DIOXIDE
NITROALDOL REACTIONS
MAGNETIC-PROPERTIES
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期刊
IF:
3.3
论文数:
3.3W
被引数:
7.5W
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