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3D structured vesicular (μAl/PTFE)/NC composites: Tailoring combustion performance through rapid phase transition fabrication
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DOI：10.1016/j.dt.2026.07.013.png)
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Abstract
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• A rapid phase-transition strategy enabled the fabrication of 3D vesicular (μAl/PTFE)/NC microspheres. • NC served as a porous scaffold to co-disperse μAl and PTFE uniformly. • PTFE introduced a pre-ignition reaction at 430–560 °C and promoted Al oxidation. • (Al85PTFE15)/NC showed the best thermal and combustion performance. • Al–F species in residues supported fluorination-assisted activation of μAl.
Keywords:
(μAl/PTFE)/NC composites
vesicular microspheres
rapid phase transition
pre-ignition reaction
fluorination-assisted combustion
energetic materials
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