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A coumarin based turn-on type fluorescent probe for the detection of Cu2+ with mechanochromic property
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DOI：10.1016/j.molstruc.2025.141938.png)
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Abstract
En 中文
This study presents the design and synthesis of a novel fluorescent probe, (Z)-N'-[[7-(diethylamino)-2-oxo-2H- chromen-4-yl]methylene]-2-hydroxybenzohydrazide (FS). FS demonstrated a pronounced turn on type cyan fluorescence upon the addition of Cu2+ in a DMSO/PBS solution (1 mM, pH = 7.4, V: V = 1:1). The detection of Cu2+ by FS displayed high selectivity, strong anti-interference capabilities, and a low detection limit of 2.46 x 10(-8) M. The binding ratio of FS to Cu2+ was determined to be 1:1 according to the Job's plot and DFT calculation while the binding constant was calculated to be 6.20 x 10(4) M-1. Additionally, the recognition mechanism of FS for Cu(2+)was further elucidated through ESI-MS and 1H NMR titration analyses. Moreover, FS exhibited mechanochromic property, transforming from yellow to orange fluorescence upon grinding, with the emission wavelength shifting from 551 nm to 597 nm. Meanwhile, the original state could be restored through fumigation with ethanol vapor, and this process was repeatable. Furthermore, FS demonstrated potential applications for Cu2+ detection and in the production of pressure-sensitive writing fluorescent display materials.
Keywords:
Coumarin
Fluorescent probe
Cu2+
Mechanochromic property
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4.7
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6.6W
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