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A robust electroactive n-dopable aromatic polyketone
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DOI：10.1002/adfm.200400291.png)
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Abstract
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A new n-dopable polyketone, poly[(5-(2,5-dihexyl-4-(thiophen-2-yl)phenyl)thiophen-2-yl)(4-ketophenyl)methanone] (PTK), is synthesized via Friedel-Crafts acylation. Though insulating in the neutral state, PTK becomes conductive upon electrochemical reduction. The stable, two-electron, fully reversible reduction is probed spectroelectrochemically and via in-situ conductivity measurements.
Keywords:
POLYTHIOPHENES
POLYANILINE
POLYMERS
FILMS
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