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A three-component hydrogen bonded framework
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DOI：10.1039/d4cc02265c.png)
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Abstract
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A porous three-component hydrogen bonded framework, 1 & sdot;biphen & sdot;TP, was prepared from a tetra-amidinium component (14+) and two different dianions, benzene-1,4-dicarboxylate (terephthalate, TP2-) and biphenyl-4,4 '-dicarboxylate (biphen2-). Interestingly, when the framework was prepared in ethanol/water, 1 & sdot;biphen & sdot;TP forms even when an excess of either dicarboxylate is present. However, when only water is used as solvent, only two-component frameworks are formed. A porous three-component hydrogen bonded framework is prepared from a tetra-amidinium cation and two different dicarboxylate anions.
Keywords:
METAL-ORGANIC FRAMEWORK
SORPTION
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4.2
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