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A versatile defect engineering strategy for room-temperature flash sintering

delete2022-07-02
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OA
AI
A
Angxuan Wu
Z
Ziyang Yan
王希林 (Xilin Wang) *
喻志阳 cover
喻志阳 (Zhiyang Yu)
R
Rongxia Huang
N
Nianping Yan
贾志东 (Zhidong Jia)
DOI:10.1007/s40145-022-0591-5delete
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Abstract

Abstract

En 中文
In this study, we reported that flash sintering (FS) could be efficiently triggered at room temperature (25 degrees C) by manipulating the oxygen concentration within ZnO powders via a versatile defect engineering strategy, fully demonstrating a promising method for the repaid prototyping of ceramics. With a low concentration of oxygen defects, FS was only activated at a high onset electric field of similar to 2.7 kV/cm, while arcs appearing on the surfaces of samples. Strikingly, the onset electric field was decreased to < 0.51 kV/cm for the activation of FS initiated, which was associated with increased oxygen concentrations coupled with increased electrical conductivity. Thereby, a general room-temperature FS strategy by introducing intrinsic structural defect is suggested for a broad range of ceramics that are prone to form high concentration of point defects.
Keywords:
flash sintering (FS)
oxygen vacancies
defect engineering
ZnO powders
electric discharge

Journal

Journal of Advanced Ceramics cover
Journal of Advanced Ceramics
IF:
16.6
Papers:
984
Citations:
9.9K

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tsinghua university
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Tsinghua Shenzhen International Graduate School
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fuzhou university
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guangdong university of technology
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