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An isolable nitrene radical anion as a nucleophilic open-shell nitrogen synthon

delete2026-07-22
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PRE
AI
Y
Yutong Jin
L
Lei Xu
S
Song Gao
谭
谭庚文 (Gengwen Tan) *
DOI：10.1016/j.chempr.2026.103162delete
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Abstract

Abstract

En 中文
• Isolated transition-metal-free nitrene radical anion in condensed phase • HOMO-SOMO inversion revealed in a nitrene radical anion • Nucleophilic reactivity enables N–Se, N–Si, and N–C bond formation

Journal

Chem cover
Chem
IF:
19.6
Papers:
2.8K
Citations:
3.0W

Organization

S
Sun Yat-Sen University
Scholars:
7.8K
Papers: 2.1K
Citations: 0
N
nanjing university
Scholars:
7.6W
Papers: 5.5W
Citations: 87
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