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Anionic chalcogen functionalised pentaphosphaferrocene complexes

delete2025-11-17
delete0
PRE
AI
D
David Konieczny
M
Mehdi El Sayed Moussa
E
Eric Mädl
S
Stephan Reichl
M
Mikhail V. Butovskiy
M
Michael Bodensteiner
A
A.V. Virovets
M
Manfred Scheer
DOI：10.1039/D5QI02065Ddelete
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Abstract

Abstract

En 中文
Ferrocene has long captivated chemists as a benchmark organometallic compound; renowed for its exceptional stability; versatile redox behaviour and synthetic flexibility. In contrast; its phosphorus analogue pentaphosphaferrocene [Cp*Fe(η 5 -P 5 )]; has received comparatively less attention despite exhibiting distinctive electronic and structural characteristics. Herein; we describe the synthesis of anionic complexes incorporating novel P 5 E (E = O; S; Se) and P 5 E 2 (E = O; S; Se and Te) mixedmain group ligands from the reactions of pentaphosphaferrocene and its reduced anionic salts [K(DME)] 2 [Cp*Fe(η 4 -P 5 )] and [K(DME)] 2 [{Cp*Fe(η 4 -P 5 )} 2 ] with KOH/K; S 8 ; Se 8 ; Me 3 NO and Na 2 Te; respectively.

Journal

Inorganic Chemistry Frontiers cover
Inorganic Chemistry Frontiers
IF:
6.4
Papers:
5.2K
Citations:
2.1W

Organization

No organization information available