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Antimony diiminopyridine complexes
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DOI：10.1039/d1dt02085d.png)
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Abstract
En 中文
The stoichiometric reactions of antimony trichloride, trimethylsilyl trifluoromethanesulfonate, and diiminopyridine ligands lead to the formation of N,N ',N ''-chelated SbCl2 cationic complexes. Methyl and phenyl substituents on the imine carbons of the ligand yielded structures with a lone pair on antimony and the hydrogen substituted variant was notably different as it forms a Menshutkin complex with meta-xylene in the solid-state.
Keywords:
TRIDENTATE LIGANDS
METAL-COMPLEXES
COORDINATION
POLYMERIZATION
CATALYSTS
HETEROCYCLES
DERIVATIVES
HALIDES
STATE
ACID
Journal
IF:
3.3
Papers:
3.3W
Citations:
7.5W