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Cage-directed skeleton rearrangement mechanism of hydrogenated polycyclic aromatic hydrocarbons to alkyl adamantanes: reaction network and hydrogen transfer on acid sites

delete2026-06-14
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PRE
AI
X
Ximo Wang
Y
Yingyi Li
G
Guogang Ren
Z
Zhenlei Zhang
J
Jiaxu Liu *
C
Changhai Liang *
C
Chuang Li *
DOI：10.1016/j.ces.2026.124449delete
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Abstract

Abstract

En 中文
• Establish the comprehensive cage-directed skeleton rearrangement network. • Post-treatment of USY verifies strong and medium BAS as the primary active centers. • D2 tracing reveals hydrogen dissociation, exchange with BAS, and reaction activation. • Large Pt nanoparticles promote hydrogen transfer and reactant accessibility.

Journal

Chemical Engineering Science cover
Chemical Engineering Science
IF:
4.3
Papers:
2.2W
Citations:
5.5W

Organization

B
beijing huairou laboratory
Scholars:
411
Papers: 147
Citations: 0
D
Dalian University of Technology
Scholars:
5.7W
Papers: 4.3W
Citations: 5.5W
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