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Catalytic photoinduced deoxygenation via B(C6F5)3-enabled oxygen atom transfer for aromatic CH amination of alkylarenes
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DOI：10.1016/j.cclet.2026.113041.png)
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Abstract
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A recent study by Ma and co-workers on the photocatalytic deoxygenative generation of N-centered radicals has been highlighted. This innovative strategy employs B(C6F5)3 as a catalytic oxygen-atom-transfer reagent, obviating the need for stoichiometric activators and avoiding the formation of organic waste. The method enables direct aromatic C(sp2)-H amination of alkylarenes, producing water as the sole byproduct, thereby offering a green and atom-economical route to valuable arylamines. Download: Download high-res image (203KB) Download: Download full-size image
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