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Chemical order engineering in high-entropy alloys for enhanced methanol oxidation reaction via optimized coordination and lattice strain
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DOI：10.1016/j.apcatb.2025.125972.png)
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Abstract
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• Pt-HEA-6/MWCNTs exhibited high activity, stability, and CO tolerance during MOR. • Reduced Pt-Pt coordination and compressive strain weaken *CO adsorption, promote C-H activation, and enhance MOR performance. • Chemical order engineering optimizes sites, lowers barriers, and curbs metal leaching, enhancing electrocatalytic activity. • Introducing metallic Ru enhances *OH adsorption and accelerates *CO detoxification, thereby freeing more active sites.
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