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Constructing the V2O3@C/S cathode -based solid-state LiS batteries

delete2025-11-14
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PRE
AI
H
Heng-xue Zhou
L
Long Yi
Q
Q. Zhong
J
Jialiang Wang
B
Bo Liang
Y
Yingbang Yao
D
Daniel Q. Tan
鲁圣国 (Sheng‐Guo Lu)
T
Tao Tao *
DOI:10.1016/j.jelechem.2025.119654delete
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Abstract

Abstract

En 中文
A novel V2O3@C/S composite cathode material is prepared via a combined strategy consisting of solution synthesis, hydrothermal treatment and high-temperature carbonization, and all solid-state lithium‑sulfur (LiS) batteries with high-performance are constructed. The obtained V2O3@C host material demonstrates excellent properties, including good structural stability, superior electrical conductivity, strong interfacial compatibility, notable sulfur adsorption and high catalytic capabilities. At a current rate of 0.1C, the V2O3@C/S cathode delivers an initial capacity of 1125 mAh g−1 with a capacity retention of 67.1 % after 150 cycles in solid-state cells at the room temperature. At 0.5C, the capacity retention still remains 45.5 % after 250 cycles. Cyclic voltammetry, electrochemical impedance spectroscopy, and Tafel analysis further demonstrate the enhanced reaction kinetics and reduced charge-transfer resistance. This work provides a promising strategy for designing the high-performance cathode materials of solid-state LiS batteries.

Journal

Journal of Electroanalytical Chemistry cover
Journal of Electroanalytical Chemistry
IF:
4.1
Papers:
1.7W
Citations:
4.0W

Organization

G
Guangdong Technion-Israel Institute of Technology
Scholars:
255
Papers: 99
Citations: 1.9K
G
guangdong university of technology
Scholars:
3.0W
Papers: 2.0W
Citations: 36