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Contribution of Severe Plastic Deformation via High-Pressure Torsion to the Hydrogen Cycle: From Hydrogen Production and Storage to Hydrogen Embrittlement
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DOI：10.3390/hydrogen7010023.png)
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Abstract
En 中文
Hydrogen is a key energy carrier for achieving carbon neutrality, yet its widespread deployment is hindered by challenges associated with efficient hydrogen production, safe and reversible hydrogen storage, and hydrogen-induced embrittlement. Severe plastic deformation processes, particularly high-pressure torsion (HPT), have emerged as a powerful approach capable of addressing these challenges through extreme grain refinement, defect engineering, phase stabilization far from equilibrium, and synthesis of novel materials. This article reviews the impact of HPT on hydrogen-related materials, covering hydrogen production, hydrogen storage, and hydrogen embrittlement resistance. For hydrogen production, HPT enables the synthesis of nanostructured, defect-rich, and compositionally complex compounds, including high-entropy oxides and oxynitrides, which exhibit enhanced hydrolytic, electrocatalytic, photocatalytic, photoelectrocatalytic, and photoreforming performance. For hydrogen storage, HPT fundamentally modifies hydrogenation activation and kinetics, and modifies thermodynamics by hydrogen binding energy engineering, enabling reversible hydrogen storage at room temperature in systems such as Mg-based and high-entropy alloys. For hydrogen embrittlement resistance, HPT under optimized conditions suppresses hydrogen-assisted fracture by engineering ultrafine grains and defects (vacancies, dislocations, Lomer-Cottrell locks, D-Frank partial dislocations, stacking faults, twins, and grain boundaries) that control hydrogen diffusion, trapping, and strain localization. By integrating insights across these three domains, this article highlights HPT as a transformative strategy for developing next-generation hydrogen materials and identifies key opportunities for future research at the intersection of severe plastic deformation and hydrogen technologies.
Keywords:
severe plastic deformation (SPD)
hydrogen storage materials
photocatalysis
electrolysis
hydrolysis
hydrogen compatibility
