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Coordination [Co2II] and [CoIIZnII] Helicates Showing Slow Magnetic Relaxation
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DOI：10.1021/acs.inorgchem.9b01334.png)
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Abstract
En 中文
The slow magnetic relaxation of Co-II ions in the elusive intermediate geometry between the trigonal prism and antiprism has been studied on the new [Co2L3](4+) and [CoZnL3](4+) coordination helicates [L is a bis(pyrazolylpyridine) ligand]. Solution paramagnetic H-1 NMR and solid-state magnetization measurements unveil single-molecule-magnet behavior with small axial anisotropy, as predicted previously.
Keywords:
SINGLE-ION-MAGNET
HIGH-SPIN CO(II)
MOLECULE MAGNETS
CROSSOVER
SYMMETRY
COMPLEX
GUEST
ANISOTROPY
BLOCKING
BARRIER
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