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Cross-Coupling Reaction with Lithium Methyltriolborate
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DOI：10.3390/molecules18010430.png)
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Abstract
En 中文
We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [MeB(OCH2)(3)CCH3]Li with aryl halides occurred in the presence of Pd(OAc)(2)/RuPhos complex in refluxing MeOH/H2O and the absence of bases.
Keywords:
cross-coupling reaction
palladium catalyst
methyltrioolborate
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