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Deciphering the effects of molar ratios and non-equal diffusion coefficients in multi-frequency electrochemical faradaic spectroscopy
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DOI：10.1016/j.elecom.2026.108187.png)
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Abstract
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• Multi-frequency analysis with qualitative insight to the system's redox state. • Kinetic analysis unaffected by molar fractions and unequal diffusion coefficients. • New equation for reliable estimation of ks without de novo simulation for every case. • Guidance for multi-frequency electrochemical faradaic spectroscopy in potentiostats.
Keywords:
Multi-frequency analysis
Quasireversible maximum
Molar fraction
Diffusion coefficients
Square-wave voltammetry
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